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Abstrak
The structure and photo-response properties of ZnO:Fe/ITO thin film synthesized using a pyrolysis method were studied in this work. ZnO:Fe/ITO thin film referred to as FZO/ITO was characterized using the X-ray diffraction (XRD) technique and current-voltage (I-V) measurements. The XRD analysis showed that the detected peaks at 30.23°, 35.15°, 37.36°, 45.18°, and 50.54° belonged to the ITO cubic phase. The I-V analyses showed that the sample had the saturation current, Schottky barrier, and sensitivity of 16.24 µA, 0.4771, and 0,90 µA respectively. The FZO/ITO gave a good response toward the light.
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Hak Cipta (c) 2024 Amrina Mustaqim -, Yeli Krisdayanti Lature, Mohamad Samsul Anrokhi, Koko Friansa, Retno Maharsi, Eka Nurfani

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Referensi
- Zhe Chuan Feng, “Handbook of Zinc Oxide and Related Materials - Devices and Nano-Engineering,” 1st ed., vol. 2, CRC Press, 2012.
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- E. Nurfani et al., “Optical properties of ZnO:Fe films deposited by spray pyrolysis with different solvents,” presented at the II INTERNATIONAL CONFERENCE “SUSTAINABLE DEVELOPMENT: AGRICULTURE, VETERINARY MEDICINE AND ECOLOGY,” Karshi, Republic of Uzbekistan, 2023, p. 020017. doi: 10.1063/5.0130389.
- N. Kumar and A. Srivastava, “Faster photoresponse, enhanced photosensitivity and photoluminescence in nanocrystalline ZnO films suitably doped by Cd,” J. Alloys Compd., vol. 706, pp. 438–446, Jun. 2017, doi: 10.1016/j.jallcom.2017.02.244.
- M. Salem, S. Akir, T. Ghrib, K. Daoudi, and M. Gaidi, “Fe-doping effect on the photoelectrochemical properties enhancement of ZnO films,” J. Alloys Compd., vol. 685, pp. 107–113, Nov. 2016, doi: 10.1016/j.jallcom.2016.05.254.
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- B. Saravanakumar, R. Mohan, K. Thiyagarajan, and S.-J. Kim, “Investigation of UV photoresponse property of Al, N co-doped ZnO film,” J. Alloys Compd., vol. 580, pp. 538–543, Dec. 2013, doi: 10.1016/j.jallcom.2013.05.014.
Referensi
Zhe Chuan Feng, “Handbook of Zinc Oxide and Related Materials - Devices and Nano-Engineering,” 1st ed., vol. 2, CRC Press, 2012.
Anderson Janotti and Chris G Van de Walle, “Fundamentals of zinc oxide as a semiconductor,” Rep. Prog. Phys., vol. 72, Oct. 2009, doi: 10.1088/0034-4885/72/12/126501.
S. S. Ghosh, C. Choubey, and A. Sil, “Photocatalytic response of Fe, Co, Ni doped ZnO based diluted magnetic semiconductors for spintronics applications,” Superlattices Microstruct., vol. 125, pp. 271–280, Jan. 2019, doi: 10.1016/j.spmi.2018.10.028.
P. Gu, X. Zhu, and D. Yang, “Structural, optical and photoelectric properties of Mn-doped ZnO films used for ultraviolet detectors,” RSC Adv., vol. 9, no. 14, pp. 8039–8047, 2019, doi: 10.1039/C9RA01099H.
S. S. Shinde, P. S. Shinde, S. M. Pawar, A. V. Moholkar, C. H. Bhosale, and K. Y. Rajpure, “Physical properties of transparent and conducting sprayed fluorine doped zinc oxide thin films,” Solid State Sci., vol. 10, no. 9, pp. 1209–1214, Sep. 2008, doi: 10.1016/j.solidstatesciences.2007.11.031.
M. A. Ciciliati, M. F. Silva, D. M. Fernandes, M. A. C. De Melo, A. A. W. Hechenleitner, and E. A. G. Pineda, “Fe-doped ZnO nanoparticles: Synthesis by a modified sol–gel method and characterization,” Mater. Lett., vol. 159, pp. 84–86, Nov. 2015, doi: 10.1016/j.matlet.2015.06.023.
T. Srinivasulu, K. Saritha, and K. T. R. Reddy, “Synthesis and characterization of Fe-doped ZnO thin films deposited by chemical spray pyrolysis,” Mod. Electron. Mater., vol. 3, no. 2, pp. 76–85, Jun. 2017, doi: 10.1016/j.moem.2017.07.001.
Fei Gao, Yong Mei Bai, Xiao Yan Liu, Li Yun Zheng, Mei Xia Li, and Juan Xie, “Microstructure and optical properties of Fe-doped ZnO thin films prepared by DC magnetron sputtering,” J. Cryst. Growth, vol. 371, pp. 126–129, May 2013.
R. Lehru et al., “Studies on electrical properties of Fe doped ZnO nanostructured oxides synthesized by sol–gel method,” Solid State Commun., vol. 336, p. 114415, Oct. 2021, doi: 10.1016/j.ssc.2021.114415.
Tamara V. Gavrilović, Miroslav D. Dramićanin, and Dragana J. Jovanović, “Chapter 2 - Synthesis of Multifunctional Inorganic Materials: From Micrometer to Nanometer Dimensions,” Nanomater. Green Energy Elsevier, no. Micro and Nano Technologies, pp. 55–81, 2018.
T. V. Gavrilović, D. J. Jovanović, and M. D. Dramićanin, “Synthesis of Multifunctional Inorganic Materials,” in Nanomaterials for Green Energy, Elsevier, 2018, pp. 55–81. doi: 10.1016/B978-0-12-813731-4.00002-3.
E. Nurfani et al., “Optical properties of ZnO:Fe films deposited by spray pyrolysis with different solvents,” presented at the II INTERNATIONAL CONFERENCE “SUSTAINABLE DEVELOPMENT: AGRICULTURE, VETERINARY MEDICINE AND ECOLOGY,” Karshi, Republic of Uzbekistan, 2023, p. 020017. doi: 10.1063/5.0130389.
N. Kumar and A. Srivastava, “Faster photoresponse, enhanced photosensitivity and photoluminescence in nanocrystalline ZnO films suitably doped by Cd,” J. Alloys Compd., vol. 706, pp. 438–446, Jun. 2017, doi: 10.1016/j.jallcom.2017.02.244.
M. Salem, S. Akir, T. Ghrib, K. Daoudi, and M. Gaidi, “Fe-doping effect on the photoelectrochemical properties enhancement of ZnO films,” J. Alloys Compd., vol. 685, pp. 107–113, Nov. 2016, doi: 10.1016/j.jallcom.2016.05.254.
Eka Nurfani, Grandprix T. M Kadja, MAK Purbayanto, and Yudhi Darma, “The role of substrate temperature on defects, electronic transitions, and dark current behavior of ZnO films fabricated by spray technique,” Mater. Chem. Phys. Elsevier, vol. 239, 2020, [Online]. Available: https://doi.org/10.1016/j.matchemphys.2019.122065
B. Saravanakumar, R. Mohan, K. Thiyagarajan, and S.-J. Kim, “Investigation of UV photoresponse property of Al, N co-doped ZnO film,” J. Alloys Compd., vol. 580, pp. 538–543, Dec. 2013, doi: 10.1016/j.jallcom.2013.05.014.