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Abstract
Chromium (Cr) compounds are found in nature in two forms, Cr (III) and Cr (VI). Analysis of Cr (VI) was determined using spectrophotometer UV-vis. A standard solution must be fresh as a standard that is usually not used repeatedly in the measurement. This study aims to determine whether the standard solution of Cr (VI) be used for a certain period until it must be disposed of. This idea is based on Cr (VI) compounds that were categorized as hazardous and toxic materials. In this study, the shelf life of standard Cr (VI) was carried out with controlled temperature and humidity in a refrigerator at 4 ℃ during the test period of two days. In this study, there was found that every hour of storage of standard Cr (VI) will observe a change in the gradient value of the regression. The model then compared with p-value resulted in only up to 7 hours of storage with a deviation of regression slope and intercept compared with initial time (T0–T7) is 0.0062 and 0.0019 which and its increases over time. From the result, it can be concluded that standard regression can be used as a model for determining the maximum storage time by comparing the regression values each time so that the seven hours storage time is the limit where the Cr (VI) that can no longer be used as a measurement standard. It concerned that standard regression could be used as a model for determining the maximum storage time by comparing the regression values each time. Keywords: Cr (VI), Modeling, Regression, Spectrophotometry UV-vis, T-Test
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- N A, C. et al. (2021) Colorimetric detection of chromium (VI) using peroxidase mimetic IONPS with 4- Aminoantipyrene and 3-Aminophenol as a chromogen. Environ. Nanotechnology, Monit. Manag. 16, 100471.
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- More, A.G. and Gupta, S.K. (2018) Predictive modelling of chromium removal using multiple linear and nonlinear regression with special emphasis on operating parameters of bioelectrochemical reactor. J. Biosci. Bioeng. 126, 205–212.
- Giyanto (2003) Comparing Two Simple Linear Regression Equations. Oseana XXVIII, 19–31.
- Wróbel, K. et al. (1997) Enhanced spectrophotometric determination of chromium (VI) with diphenylcarbazide using internal standard and derivative spectrophotometry. Talanta 44, 2129–2136.
- Supriyanto, R. (2011) Speciation Analysis Study of Cr (III) and Cr (VI) Metal Ions With Tannic Acid From Gambir Extract Using UV-VIS Spectrometry. J. Sains MIPA 17, 35–42.
- Onchoke, K.K. and Sasu, S.A. (2016) Determination of Hexavalent Chromium (Cr(VI)) Concentrations via Ion Chromatography and UV-Vis Spectrophotometry in Samples Collected from Nacogdoches Wastewater Treatment Plant, East Texas (USA). Adv. Environ. Chem.1–10.
References
Wise, J.P. et al. (2022) Current understanding of hexavalent chromium [Cr(VI)] neurotoxicity and new perspectives. Environ. Int. 158, 106877.
N A, C. et al. (2021) Colorimetric detection of chromium (VI) using peroxidase mimetic IONPS with 4- Aminoantipyrene and 3-Aminophenol as a chromogen. Environ. Nanotechnology, Monit. Manag. 16, 100471.
Ramírez-Quesada, M.M. et al. (2021) New advances in the method validation, extraction methods and measurement uncertainty for the determination of water-soluble hexavalent chromium in hydraulic cement. Talanta 232.
Oliveira, H. (2012) Chromium as an Environmental Pollutant: Insights on Induced Plant Toxicity. J. Bot. 2012, 1–8.
Coyte, R.M. et al. (2020) Occurrence and distribution of hexavalent chromium in groundwater from North Carolina, USA. Sci. Total Environ. 711, 135135.
El-Shahawi, M.S. et al. (2005) Chemical speciation of chromium(III,VI) employing extractive spectrophotometry and tetraphenylarsonium chloride or tetraphenylphosphonium bromide as ion-pair reagent. Anal. Chim. Acta 534, 319–326.
More, A.G. and Gupta, S.K. (2018) Predictive modelling of chromium removal using multiple linear and nonlinear regression with special emphasis on operating parameters of bioelectrochemical reactor. J. Biosci. Bioeng. 126, 205–212.
Giyanto (2003) Comparing Two Simple Linear Regression Equations. Oseana XXVIII, 19–31.
Wróbel, K. et al. (1997) Enhanced spectrophotometric determination of chromium (VI) with diphenylcarbazide using internal standard and derivative spectrophotometry. Talanta 44, 2129–2136.
Supriyanto, R. (2011) Speciation Analysis Study of Cr (III) and Cr (VI) Metal Ions With Tannic Acid From Gambir Extract Using UV-VIS Spectrometry. J. Sains MIPA 17, 35–42.
Onchoke, K.K. and Sasu, S.A. (2016) Determination of Hexavalent Chromium (Cr(VI)) Concentrations via Ion Chromatography and UV-Vis Spectrophotometry in Samples Collected from Nacogdoches Wastewater Treatment Plant, East Texas (USA). Adv. Environ. Chem.1–10.