Main Article Content

Abstract

Di era sekarang, pola hidup sehat makin digemari dibarengi dengan makin tercemarnya lingkungan. Kesadaran akan makanan yang aman untuk dikonsumsi semakin meningkat. Pencemaran pada lingkungan berdampak pada tercemarnya bahan makanan. Metal-organic frameworks (MOFs) adalah material baru yang memiliki banyak potensi aplikasi, salah satunya adalah untuk analisis makanan. MOF memiliki karakteristik yang unik, seperti pori-pori yang besar dan luas permukaan yang tinggi, yang membuatnya cocok untuk digunakan dalam proses ekstraksi, Metode magnetic solid phase extraction (MSPE) adalah metode ekstraksi yang menggunakan material magnetik untuk menyerap dan mengumpulkan analit dari larutan. Metode ini memiliki beberapa keunggulan, seperti efisiensi ekstraksi yang tinggi, kemudahan pemisahan analit dari material magnetik, dan biaya yang relatif rendah. Pada review kali ini, akan dibahas mengenai cara kerja metode MSPE, perbandingan MOFs yang digunakan pada bermacam sampel berdasarkan penelitian; dan MOFs yang terbaik yang dapat digunakan untuk mendeteksi dan menghilangkan kontaminan yang ada pada makanan.

Article Details

How to Cite
Pemanfaatan MOF (Metal Organic Framework) Untuk Analisis Makanan Dengan Metode MSPE (Magnetic Solid Phase Extraction): Sebuah Telaah Pustaka. (2024). RAFFLESIA JOURNAL OF NATURAL AND APPLIED SCIENCES, 4(1), 252–267. https://doi.org/10.33369/rjna.v4i1.32533

References

    [1]. Hartini E. Kadar plumbum (pb) dalam umbi bawang merah di kecamatan kersana
    kabupaten brebes. Jurnal Visikes. 2011;10(1):69-75.
    [2]. Habibah N, Dhyanaputri IG, Karta IW, Dewi NN. Analisis Kuantitatif Kadar Nitrit
    dalam Produk Daging Olahan di Wilayah Denpasar Dengan Metode Griess Secara
    Spektrofotometri. International Journal of Natural Science and Engineering. 2018
    Apr 18;2(1):1-9.
    [3]. Bradshaw D, Garai A, Huo J. Metal–organic framework growth at functional
    interfaces: thin films and composites for diverse applications. Chemical Society
    Reviews. 2012;41(6):2344-81.
    [4]. Pasaribu MH, Karelius K, Ramdhani EP, Agnestisia R, Pereiz Z, Toepak EP. Synthesis
    of Mil-100 (Fe)@ Fe3O4 Composite using Zircon Mining Magnetic Waste as an
    Adsorbent for Methylene Blue Dye. InBIO Web of Conferences. 2023 (Vol. 70, p.
    02010). EDP Sciences.
    [5]. Rocío-Bautista P, Pino V, Ayala JH, Pasán J, Ruiz-Pérez C, Afonso AM. A magneticbased
    dispersive micro-solid-phase extraction method using the metal-organic
    framework HKUST-1 and ultra-high-performance liquid chromatography with
    fluorescence detection for determining polycyclic aromatic hydrocarbons in waters
    and fruit tea infusions. Journal of Chromatography A. 2016 Mar 4;1436:42-50.
    [6]. Zhou Z, Fu Y, Qin Q, Lu X, Shi X, Zhao C, Xu G. Synthesis of magnetic mesoporous
    metal-organic framework-5 for the effective enrichment of malachite green and
    crystal violet in fish samples. Journal of Chromatography A. 2018 ;1560:19-25.
    [7]. Vatta LL, Sanderson RD, Koch KR. Magnetic nanoparticles: Properties and potential
    applications. Pure and applied chemistry. 2006 ;78(9):1793-801.
    [8]. Hu Y, Lian H, Zhou L, Li G. In situ solvothermal growth of metal–organic framework-5
    supported on porous copper foam for noninvasive sampling of plant volatile sulfides.
    Analytical chemistry. 2015 ;87(1):406-12.
    [9]. Herrero-Latorre C, Barciela-García J, García-Martín S, Peña-Crecente RM, Otárola-
    Jiménez J. Magnetic solid-phase extraction using carbon nanotubes as sorbents: A
    review. Analytica Chimica Acta. 2015 ;892:10-26.
    [10].Płotka-Wasylka J, Szczepańska N, de La Guardia M, Namieśnik J. Miniaturized solidphase
    extraction techniques. TrAC Trends in Analytical Chemistry. 2015 ;73:19-38.
    [11].Wierucka M, Biziuk M. Application of magnetic nanoparticles for magnetic solidphase
    extraction in preparing biological, environmental and food samples. TrAC
    Trends in Analytical Chemistry. 2014 ;59:50-8.
    [12].Shi XR, Chen XL, Hao YL, Li L, Xu HJ, Wang MM. Magnetic metal-organic frameworks
    for fast and efficient solid-phase extraction of six Sudan dyes in tomato sauce.
    Journal of Chromatography B. 2018 ;1086:146-52.
    [13].Huang C, Qiao X, Sun W, Chen H, Chen X, Zhang L, Wang T. Effective extraction of
    domoic acid from seafood based on postsynthetic-modified magnetic zeolite
    imidazolate framework-8 particles. Analytical chemistry. 2019 Jan 4;91(3):2418-24.
    [14].Wang X, Wang S, Cai Z. The latest developments and applications of mass
    spectrometry in food-safety and quality analysis. TrAC Trends in Analytical
    Chemistry. 2013 ;52:170–85.
    [15].Magri A, Petriccione M, Gutiérrez TJ. Metal-organic frameworks for food applications:
    A review. Food Chemistry. 2021 ;354:129533.
    [16].Han S, Wei Y, Valente C, Lagzi I, Gassensmith JJ, Coskun A, Stoddart JF, Grzybowski
    BA. Chromatography in a single metal− organic framework (MOF) crystal. Journal of
    the American Chemical Society. 2010 ;132(46):16358-61.
    [17].Wang PL, Xie LH, Joseph EA, Li JR, Su XO, Zhou HC. Metal–organic frameworks for
    food safety. Chemical reviews. 2019 ;119(18):10638-90.
    [18].Hu Y, Huang Z, Liao J, Li G. Chemical bonding approach for fabrication of hybrid
    magnetic metal–organic framework-5: high efficient adsorbents for magnetic
    enrichment of trace analytes. Analytical chemistry. 2013 ;85(14):6885-93.
    [19].Taghizadeh, M., Asgharinezhad, A.A., Pooladi, M., Barzin, M., Abbaszadeh, A. and
    Tadjarodi, A. A novel magnetic metal organic framework nanocomposite for
    extraction and preconcentration of heavy metal ions, and its optimization via
    experimental design methodology. Microchimica Acta, 2013. 180, pp.1073-1084.
    [20].Lan H, Gan N, Pan D, Hu F, Li T, Long N, Shen H, Feng Y. Development of a novel
    magnetic molecularly imprinted polymer coating using porous zeolite imidazolate
    framework-8 coated magnetic iron oxide as carrier for automated solid phase
    microextraction of estrogens in fish and pork samples. Journal of Chromatography A.
    2014 ;1365:35-44.
    [21].Sohrabi MR, Matbouie Z, Asgharinezhad AA, Dehghani A. Solid phase extraction of
    Cd(II) and Pb(II) using a magnetic metal-organic framework, and their
    determination by FAAS. Microchimica Acta. 2013;180(7–8):589–97.
    [22].Xia L, Liu L, Lv X, Qu F, Li G, You J. Towards the determination of sulfonamides in
    meat samples: A magnetic and mesoporous metal-organic framework as an efficient
    sorbent for magnetic solid phase extraction combined with high-performance liquid
    chromatography. Journal of Chromatography A. 2017;1500:24-31.
    [23].Li Z, Qi M, Tu C, Wang W, Chen J, Wang AJ. Magnetic Metal-Organic
    Framework/Graphene Oxide-Based Solid-Phase Extraction Combined with
    Spectrofluorimetry for the Determination of Enrofloxacin in Milk Sample. Food Anal
    Methods. 2017;10(12):4094–103.
    [24].Su H, Lin Y, Wang Z, Wong YLE, Chen X, Chan TWD. Magnetic metal–organic
    framework–titanium dioxide nanocomposite as adsorbent in the magnetic solidphase
    extraction of fungicides from environmental water samples. Journal of
    Chromatography A. 2016;1466:21–8.
    [25].Zhou Q, Lei M, Li J, Liu Y, Zhao K, Zhao D. Magnetic solid phase extraction of N- and
    S-containing polycyclic aromatic hydrocarbons at ppb levels by using a zerovalent
    iron nanoscale material modified with a metal organic framework of type Fe@MOF-
    5, and their determination by HPLC. Microchimica Acta. 2017;184(4):1029–36.
    [26].Chen X, Ding N, Zang H, Yeung H, Zhao RS, Cheng C, dkk. Fe3O4@MOF core–shell
    magnetic microspheres for magnetic solid-phase extraction of polychlorinated
    biphenyls from environmental water samples. Journal of Chromatography A.
    2013;1304:241–5.
    [27].Liu Y, Gao Z, Wu R, Wang Z, Chen X, Chan TWD. Magnetic porous carbon derived
    from a bimetallic metal–organic framework for magnetic solid-phase extraction of
    organochlorine pesticides from drinking and environmental water samples. Journal
    of Chromatography A. 2017;1479:55–61.
    [28].Liang L, Wang X, Sun Y, Ma P, Li X, Piao H, dkk. Magnetic solid-phase extraction of
    triazine herbicides from rice using metal-organic framework MIL-101(Cr)
    functionalized magnetic particles. Talanta. 2018;179:512–9.
    [29].Hassanpour A, Hosseinzadeh-Khanmiri R, Babazadeh M, Abolhasani J, Ghorbani-
    Kalhor E. Determination of heavy metal ions in vegetable samples using a magnetic
    metal–organic framework nanocomposite sorbent. Food Additives & Contaminants:
    Part A. 2015 ;32(5):725-36.
    [30].Wang Y, Chen H, Tang J, Ye G, Ge H, Hu X. Preparation of magnetic metal organic
    frameworks adsorbent modified with mercapto groups for the extraction and
    analysis of lead in food samples by flame atomic absorption spectrometry. Food
    Chemistry. 2015 ;181:191-7.
    [31].Rocío-Bautista P, Pino V, Ayala JH, Pasán J, Ruiz-Pérez C, Afonso AM. A magneticbased
    dispersive micro-solid-phase extraction method using the metal-organic
    framework HKUST-1 and ultra-high-performance liquid chromatography with
    fluorescence detection for determining polycyclic aromatic hydrocarbons in waters
    and fruit tea infusions. Journal of Chromatography A. 2016;1436:42–50.
    [32].Ghorbani-Kalhor E, Hosseinzadeh-Khanmiri R, Babazadeh M, Abolhasani J,
    Hassanpour A. Synthesis and application of a novel magnetic metal-organic
    framework nanocomposite for determination of Cd, Pb, and Zn in baby food samples.
    Canadian Journal of Chemistry. 2015;93(5):518-25..
    [33].Ma J, Yao Z, Hou L, Lu W, Yang Q, Li J, dkk. Metal organic frameworks (MOFs) for
    magnetic solid-phase extraction of pyrazole/pyrrole pesticides in environmental
    water samples followed by HPLC-DAD determination. Talanta. 2016;161:686–92.
    [34].Lu N, He X, Wang T, Liu S, Hou X. Magnetic solid-phase extraction using MIL-
    101(Cr)-based composite combined with dispersive liquid-liquid microextraction
    based on solidification of a floating organic droplet for the determination of
    pyrethroids in environmental water and tea samples. Microchemical Journal.
    2018;137:449–55.
    [35].Hao L, Wang C, Wu Q, Li Z, Zang X, Wang Z. Metal–organic framework derived
    magnetic nanoporous carbon: novel adsorbent for magnetic solid-phase extraction.
    Analytical chemistry. 2014;86(24):12199-205.