Main Article Content
Abstract
The aims of this research is improve stability and sensitivity of silver nanoparticles (NPP) immobilizatied on filter paper. Silver nanoparticles synthesized by reducing the ascorbic acid using a chemical reduction method. Immobilization NPP on filter paper is done with the technique of immobilization (immunosystem) is the process of molecular bonding reagent in supporting materials, so physically bound NPP the surface of filter paper is composed of cellulose fibers. The results obtained for the stability of immobilization NPP on filter paper can be last up to stable 60-daywhile liquid NPP stability can only last for 30 days. To maintained the stability ofimmobilization on filter paper is saved in a closed box. For the determination of sensitivity of immobilization NPP in the filter paper test is performed against the mercury (II) ion with each different concentrations. The results obtained for sensitivity of immobilization NPP on the filter paper is analyzed in digital image can be detect mercury (II) ion until the concentration of ppb. The results of measurement Limit of Detection (LOD) or limit the smallest NPP can detect mercury (II) ion is under 0.863 ppb, while liquid NPP able to detect only concentration 1.448 ppb.. The results of this research NPP immobilization on filter paper can be an alternative to increasingstability and sensitivity of NPP compared with liquid NPP, and can be applied into the colourimetry indicator is inexpensive and practical to analysis of mercury (II) ion in the digital image.
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References
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References
Purnomo, S.R. Sintesis Nanopartikel Perak Dengan Metode Biologi MenggunakanEkstrak Tanaman Sambiloto (Andrographis paniculata Ness). Jurnal Buletin Fisika. 2017. 18(1): 6-11
Ariningsih, E., Prospek Penerapan Teknologi Nano Dalam Pertanian Dan Pengolahan Pangan Di Indonesia , Forum Penelitian Agro Ekonomi, 2016: 34 (1): 1-20.
Ahmad, M.B., Mei, Y.t., Kamyar, S., Mohd, Z.h., Jenn, J.L. Green Synthesis and Characterization of Silver/Chitosan/ Polyethylene Glycol Nanocomposites without any Reducing Agent, International Journal Molecular Sciences. 2011. 12 (8): 4872-4884
Sari, P.I., M.Lutfi Firdaus, Rina Elvia., Pembuatan Nanopartikel Perak (NPP) Dengan Bioreduktor Ekstrak Buah Muntingia calabura L Untuk Analisis Logam Merkuri , Alotrop, 2017: 1(1): 20-26
Haryono, A., Dewi Sondari, S. Budi Harmami, M. Randy. Sintesa Nanopartikel Perak dan Potensi Aplikasinya. Jurnal Riset Industri. 2008. 2(3): 156-163
Maryani. D., M.Lutfi Firdaus, Nurhamidah., Biosintesis Nanopartikel Perak Menggunakan Ekstrak Buah Passiflora flavicarva ( Markisa) Untuk Medeteksi Logam Berat, Alotrop, 2017: 1(1): 49-54.
Apriandanu, DOB, S. Wahyuni, S. Hadisaputro, Harjono. Sintesis Nanopartikel Perak Menggunakan Metode Poliol Dengan Agen Stabilisator Polivinilalkohol (PVA). Jurnal MIPA UNS. 2013. 36(2): 157-168.
Yani, R.A., Iwantono , Akrajas Ali Umar, Penumbuhan Dan Karakterisasi Nanopartikel Perak Pada Substrat Padat, JOM FMIPA, 2014: 1(2): 103-109.
Rismiarti, Z., Renny, I. Karakterisasi Metode Paper Analytical Device Berbasis Pencitraan Digital Untuk Deteksi Kadmium. Jurnal Chemistry Progress. 2017. 10(2): 52-57.
Chen, G.H., Wei, Y.C., Yu, C.Y., Chia, W.W., Huan, T.C., Chien, F.C. Detection of Mercury (II) Ions Using Colorimetric Gold Nanoparticles on Paper-Based Analytical Devices. Jurnal Analytical Chemistry. 2014. 16(1): 7-20
Chaiyo, S., W., Siangproh., A.Aplux., O. Chailapakul. Highly Selective And Sensitive Paper-Based Colorimetric Sensor Using Thiosulfate Catalytic Etching of Silver Nanoplates For Trace Determination of Copper Ions. AnalyticaChimica Acta. 2015. 866(25): 75–83
Marzo,Am.L., J.Pons, D.A.Blake., A. Merkoci, All-Integrated and Highly Sensitive Paper Based Device with Sample Treatment Platform for Cd2+ Immuno detection in Drinking/ Tap Waters. Analytica Chemistry, 2013:85(7): 3532 ? 3538
Wahyudi, T., Sugiyana, D., Helmy, Q., Sintesis Nanopartikel Perak dan Uji Aktivitasnya terhadap Bakteri E. coli dan S. aureus. Arena Tekstil, 2011: 26(1): 1-60
Chen, G.H., Wei, Y.C., Yu, C.Y., Chia, W.W., Huan, T.C., Chien, F.C. Detection of Mercury (II) Ions Using Colorimetric Gold Nanoparticles on Paper-Based Analytical Devices. Jurnal Analytical Chemistry. 2014. 16(1): 7-20
Martinez, A. W., Scott T. Phillips, George M.Whitesides. Diagnostics for The Developing World: Microfluidic Paper-Based Analytical Devices. InternationalJournal Analytical Chemistry Feature.2010. 82(1): 3-10
Adriansyah, R. , M. Lutfi Firdaus, Elvinawati., Analisis Hg2+ Dengan Menggunakan Nanopartikel Perak (NPP) Sebagai Indikator Kolorimetri Dengan Metode Spektrofotometri , Alotrop , 2017: 1(2) : 136-143
Mallasis, L., Dreyfus, R., Murphy, R. J., Hough, L. A., Donnio, B., Muray, C. B. One-Step Green Synthesis of Gold and Silver Nanoparticles with Ascorbic Acid and Their Versatile Surface Post-Functionalization. Journal Royal Societyof Chemistry. 2016: 6(39): 1-9
Firdaus M.L., Ikka, F., Santhy, W., Yeni, W.H., Renat, K., Jason A.M., Hajime, O., Toshitaka, G. Colorimetric Detection of Mercury (II) Ion In Aqueous Solution Using Silver Nanoparticle. AnalyticalSciences. 2017. 33(7): 831-837
Rajabiah, N., Surface Plasmon Resonance (SPR) Phenomenon of the Oxidizing and Reducing Polypyrrole, TURBO , 2016: 5
( 2): 149-154.
Xiong,J.,Wang,Y.,Xue,Q.,Wu,X. Synthesis of Highly Stable Dispersions of Nanosized Copper Particles using L-ascorbic acid. Journal Royal Society of Chemistry,2011: 13(4): 900-904
Lee, S.Y., Hee Jin Kim, Rajkumar Patel, Se Joon Im, Silver nanoparticles immobilized on thin film composite polyamide membrane: Characterization, nanofiltration, antifouling properties, Polymers for Advanced Technologies , 2007: 18(7):562 – 568.