Main Article Content
Abstract
Nanopartikel logam mulia, seperti emas dan perak, saat ini menjadi trend topik penelitian karena kemampuannya yang istimewa dalam mendeteksi berbagai analit seperti logam berat. Hal ini disebabkan oleh sifat unik nanopartikel logam mulia yang disebut dengan surface plasmon resonance, yang salah satunya disebabkan oleh kecilnya ukuran serta besarnya luas permukaan nanopartikel logam mulia. Selain itu, nanopartikel logam mulia juga memiliki kelebihan lain, seperti mudahnya prosedur kerja, biaya pembuatan yang ekonomis, cukup selektif dan sensitif. Dalam artikel ini, kami menuliskan hasil penelitian dari beberapa nanopartikel logam mulia, khususnya logam perak dan emas. Logam berat yang diteliti diantaranya adalah Pb, Cr, dan Hg. Mekanisme yang terjadi dalam mendeteksi kadar logam berat menggunakan nanopartikel logam mulia secara kolorimetri adalah karena adanya perubahan warna dari nanopartikel ketika bergabung dengan logam berat. Metode yang digunakan adalah reduksi secara kimia serta deteksi menggunaka spektrofotometer UV-Visible. Perubahan warna dari sensor nanopartikel disebabkan oleh reaksi reduksi – oksidasi atau pun rekasi kimia lainnya seperti terbentuknya ikatan hidrogen dan gaya tarik menarik Van der Walls antara analit dengan nanopartikel. Selain untuk menentukan kadar logam berat di dalam sampel lingkungan, metode ini juga bisa dikembangkan lebih lanjut untuk analit lainnya dan dari sampel makanan atau pun untuk bidang biomedis.
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References
- Alam MN, Chatterjee A et al (2015) Burmese grape fruit juice can trigger the “logic gate”-like colorimetric sensing behavior of Ag nanoparticles towards toxic metal ions. RSC Adv 5(30):23419–23430.
- Al Qodri, I., Sipriyadi, S., & Ruyani, A. (2020). Isolation of Mercury Reducing Bacteria from Gold Mining waste that has the Potential as a Chromium Bioremediation Agent. Bencoolen Journal of Science Education and Technology, 1(1), 19-24.
- Annadhasan M, Muthukumarasamyvel T et al (2014) Green synthesized silver and gold nanoparticles for colorimetric detection of Hg2+, Pb2+, and Mn2+ in aqueous medium. ACS Sustain Chem Eng 2(4):887–896.
- Azharuddin, M., Zhu, G. H., Das, D., Ozgur, E., Uzun, L., Turner, A. P. F., Patra, H. K., (2019), A repertoire of biomedical applications of noble metal nanoparticles, Chemical Communications, 55(49), 6964-6996.
- Cheon J, Park W (2016) Green synthesis of silver nanoparticles stabilized with mussel-inspired protein and colorimetric sensing of lead (II) and copper (II) ions. Int J Mol Sci 17(12):2006.
- Devnani H, Satsangee S (2015) Green gold nanoparticle modified anthocyanin-based carbon paste electrode for voltammetric determinationof heavy metals. Int J Environ Sci Technol 12(4):1269–1282.
- Firdaus M, Andriana S et al (2017) Green synthesis of silver nanoparticles using Carica papaya fruit extract under sunlight irradiation and their colorimetric detection of mercury ions. Journal of Physics: Conference Series, IOP Publishing.
- Luo Y, Shen S et al (2015) Green synthesis of silver nanoparticles in xylan solution via Tollens reaction and their detection for Hg 2+, Nanoscale 7(2):690–700.
- Ravi SS, Christena LR et al (2013) Green synthesized silver nanoparticles for selective colorimetric sensing of Hg 2+ in aqueous solution at wide pH range. Analyst 138(15):4370–4377.
- Tirado-Guizar A, Rodriguez-Gattorno G et al (2017) Eco-friendly synthesis of egg-white capped silver nanoparticles for rapid, selective, and sensitive detection of Hg (II). MRS Commun 7(3): 695-700.
- B. V. Enustun and J. Turkevich, “Coagulation of colloidal gold,” J. Am. Chem. Soc., vol. 85, pp. 3317–3328, 1963.
- Zhang B, Chen J et al (2016) Facile and green fabrication of size-controlled AuNPs/CNFs hybrids for the highly sensitive simultaneous detection of heavy metal ions. ElectrochimActa 196:422–430.
- Zhao, X., Zhao, H., Yan, L., Li, N., Shi, J., & Jiang, C. (2020). Recent developments in detection using noble metal nanoparticles. Critical Reviews in Analytical Chemistry, 50(2), 97-110.
References
Alam MN, Chatterjee A et al (2015) Burmese grape fruit juice can trigger the “logic gate”-like colorimetric sensing behavior of Ag nanoparticles towards toxic metal ions. RSC Adv 5(30):23419–23430.
Al Qodri, I., Sipriyadi, S., & Ruyani, A. (2020). Isolation of Mercury Reducing Bacteria from Gold Mining waste that has the Potential as a Chromium Bioremediation Agent. Bencoolen Journal of Science Education and Technology, 1(1), 19-24.
Annadhasan M, Muthukumarasamyvel T et al (2014) Green synthesized silver and gold nanoparticles for colorimetric detection of Hg2+, Pb2+, and Mn2+ in aqueous medium. ACS Sustain Chem Eng 2(4):887–896.
Azharuddin, M., Zhu, G. H., Das, D., Ozgur, E., Uzun, L., Turner, A. P. F., Patra, H. K., (2019), A repertoire of biomedical applications of noble metal nanoparticles, Chemical Communications, 55(49), 6964-6996.
Cheon J, Park W (2016) Green synthesis of silver nanoparticles stabilized with mussel-inspired protein and colorimetric sensing of lead (II) and copper (II) ions. Int J Mol Sci 17(12):2006.
Devnani H, Satsangee S (2015) Green gold nanoparticle modified anthocyanin-based carbon paste electrode for voltammetric determinationof heavy metals. Int J Environ Sci Technol 12(4):1269–1282.
Firdaus M, Andriana S et al (2017) Green synthesis of silver nanoparticles using Carica papaya fruit extract under sunlight irradiation and their colorimetric detection of mercury ions. Journal of Physics: Conference Series, IOP Publishing.
Luo Y, Shen S et al (2015) Green synthesis of silver nanoparticles in xylan solution via Tollens reaction and their detection for Hg 2+, Nanoscale 7(2):690–700.
Ravi SS, Christena LR et al (2013) Green synthesized silver nanoparticles for selective colorimetric sensing of Hg 2+ in aqueous solution at wide pH range. Analyst 138(15):4370–4377.
Tirado-Guizar A, Rodriguez-Gattorno G et al (2017) Eco-friendly synthesis of egg-white capped silver nanoparticles for rapid, selective, and sensitive detection of Hg (II). MRS Commun 7(3): 695-700.
B. V. Enustun and J. Turkevich, “Coagulation of colloidal gold,” J. Am. Chem. Soc., vol. 85, pp. 3317–3328, 1963.
Zhang B, Chen J et al (2016) Facile and green fabrication of size-controlled AuNPs/CNFs hybrids for the highly sensitive simultaneous detection of heavy metal ions. ElectrochimActa 196:422–430.
Zhao, X., Zhao, H., Yan, L., Li, N., Shi, J., & Jiang, C. (2020). Recent developments in detection using noble metal nanoparticles. Critical Reviews in Analytical Chemistry, 50(2), 97-110.