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Red Palm Oil Olein (RPOO), yang diperoleh dari pengolahan Crude Palm Oil (CPO) dapat menjadi sumber provitamin A yang potensial karena karoten yang tinggi. Water degumming dan Alkali refining merupakan salah satu alternatif metode yang tidak banyak digunakan untuk menghilangkan gum dan Asam Lemak Bebas (ALB) pada pembuatan RPOO dengan suhu pemanasan yang relative rendah. Penelitian ini bertujuan untuk menentukan pengaruh penambahan jumlah NaOH saat netralisasi terhadap rendemen RPOO, kadar ALB, kandungan β-karoten, vitamin A dan tingkat kesukaan pada RPOO. Penelitian ini menggunakan Rancangan Acak Lengkap (RAL) dengan satu faktor perlakuan yaitu variasi penambahan jumlah NaOH. Hasil penelitian menunjukkan bahwa variasi penambahan jumlah NaOH berpengaruh nyata terhadap turunnya kandungan ALB RPOO menjadi berkisar antara 0,24 s/d 0,07. Kandungan β-karoten yang dihasilkan berkisar antara (635,87 s/d 645,54 ppm) dan kandungan provitamin A yaitu berkisar antara (105,97 s/d 107,59 μgRE). Selain itu, rendemen RPOO mengalami penurunan dengan peningkatan penggunaan NaOH yaitu berkisar antara (53,24 s/d 42,26%). Uji organoleptik menunjukkan bahwa penambahan NaOH berpengaruh nyata terhadap tingkat kesukaan terhadap warna, dan aroma RPOO. Peningkatan penggunaan NaOH pada alkali refining mampu menghasilkan RPOO dengan kualitas yang baik, akan tetapi pada saat yang bersamaan dapat menurunkan rendeman RPOO yang dihasilkan.
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Hak Cipta (c) 2023 Ilham Agus Saputra Saputra, Budiyanto Budiyanto, Devi Silsia Silsia

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Referensi
- Arita, S., Anindya, S. A., & Hiranda, W. (2009). Effect of Addition of Acid on the Process of Refining Coarse Castor Oil. Jurnal Teknik Kimia, 16(2), 58–65.
- Asyti, F., Oktariani, dan P. M. A. (2020). Kualitas Blend Kelapa Kopra dan Minyak Kelapa Sawit Ditinjau Dari Kadar Air, Kadar Asam Lemak Bebas dan Bilangan Peroksida. Jurnal Riset Kimia, 11(1), 8275–8279.
- Bohari, B., Muhadir, M., & Rahmadi, A. (2018). Vacuum evaporation and nitrogen-assisted deodorization affects the antioxidant capacity in the olein fraction of red palm oil and its emulsion products [version 1; peer review: 1 approved with reservations]. F1000Research, 7. https://doi.org/10.12688/F1000RESEARCH.16545.1
- Budiyanto, B., Silsia, D., & Napitupulu, A. (2019). Alternatif Fortification Vitamin A for Lactating Mother Using Siomay Sauce Enriched with Red Palm Oil. AGRITROPICA : Journal of Agricultural Sciences, 2(1), 13–25. https://doi.org/10.31186/j.agritropica.2.1.13-25
- Budiyanto, Silsia, D., & Fahmi. (2012). Kajian Pembuatan Red Palm Olein(RPOO) Dengan Bahan Baku Minyak Kasar Yang Diambil Dari Beberapa Stasiun Pengolahan Crude Palm Oil. Seminar Nasional Menuju Pertanian Yang Berdaulat, Fakultas Pertanian Universitas Bengkulu, 539–551.
- Burri, B. J. (2012). Evaluating Global Barriers to the Use of Red Palm Oil as an Intervention Food to Prevent Vitamin A Deficiency. Comprehensive Reviews in Food Science and Food Safety, 11(2), 221–232. https://doi.org/10.111/j.15414337.2011.00181.x
- Chompoo, M, D. Nanthina, and P. R. (2019). Effect Of Chemical Process on Physicochemical Properties of Red Palm Oil. Journal Science Technology, 41(3), 513–521.
- Chompoo, M., Damrongwattanakool, N., & Raviyan, P. (2019). Effect of chemical degumming process on physicochemical properties of red palm oil. Songklanakarin J. Sci. Technol., 41(3), 513–521.
- Dijkstra, A. J. (2020). About water degumming and the hydration of non-hydratable phosphatides Hypothesis Paper About water degumming and the hydration of non-hydratable phosphatides. October. https://doi.org/10.1002/ejlt.201600496
- Kurniati, Y., & Susanto, W. H. (2015). Pengaruh basa NaOH dan kandungan ALB CPO terhadap kualitas minyak kelapa sawit pasca netralisasi t of NaOH and Content of Free Fatty Acid ( FFA ) on. Jurnal Pangan Dan Agroindustri., 3(1), 193–202.
- Martianto, D., Andarwulan, N., & Putranda, Y. (2018). Retensi Fortifikan Vitamin A Dan Β-Karoten Dalam Minyak Goreng Sawit Selama Pemasakan. Jurnal Teknologi Dan Industri Pangan, 29(2), 127–136. https://doi.org/10.6066/jtip.2018.29.2.127
- Maryuningsih, R. D., & Nurtama, B. (2021). Pemanfaatan Karotenoid Minyak Sawit Merah untuk Mendukung Penanggulangan Masalah Kekurangan Vitamin A di Indonesia.
- Musyaroh, M., & Hidayat, N. (2018). The Effect of Stirring Length Time and NaOH Concentration on the Neutralization Process of Superworm Cooking Oil Purification. Industria: Jurnal Teknologi Dan Manajemen Agroindustri, 7(2), 81–88. https://doi.org/10.21776/ub.industria.2018.007.02.2
- Ping, B. T. Y., Idris, C. A. C., & Maurad, Z. A. (2020). Oxidative stability of refined red palm olein under two Malaysian storage conditions. Journal of Oleo Science, 69(10), 1209–1218. https://doi.org/10.5650 /jos.ess20045
- Riyadi, A., Muchtadi, T. R., Andarwulan, N., & Haryati, T. (2016). Pilot Plant Study of Red Palm Oil Deodorization Using Moderate Temperature. Agriculture and Agricultural Science Procedia, 9, 209–216. https://doi.org/10.1016/j.aaspro.2016.02.129
- Robiyansyah, Zuidar, A. S., & Hidayati, S. (2017). Diterima : 27 Januari 2017 Disetujui : 1 Maret 2017. Jurnal Teknologi & Industri Hasil Pertanian, 22(1), 11–20.
- Rohmah, M., Rahmadi, A., Yanti, I., Jannah, S. M., Bohari, & Supratman, U. (2021). Quantitation and optimization of β-carotene and α-tocopherol in emulsion prototype with reversed-phase chromatography. Food Research, 5(2), 290–297. https://doi.org/10.26656/fr.2017.5(2).518
- Sumarna, D., Sumarlan, S. H., Wijaya, S., & Hidayat, N. (2022). Processing of Olein Fraction Red Palm Oil with Minimal Refining Method and Optimization of Deodorization Process. Proceedings of the International Conference on Tropical Agrifood, Feed and Fuel (ICTAFF 2021), 17(Ictaff 2021), 167–175. https://doi.org/10.2991/absr.k.220102.026
- Sumarna, D., Wake, L. S., Suprapto, H., Karakteristik, S., Sawit, M., Karakteristik, S., Sawit, M., Dari, M., Cpo, K., & Palm, C. (2019). Studi Karakteristik Minyak Sawit Merah dari Pengolahan Konvensional CPO (Crude Palm Oil). Jurnal Teknologi Pertanian Universitas Mulawarman, 12(2), 35–38.
- Surhaini, S. M., & Yulia, A. (2014). Stabilitas Termal Minuman Emulsi Dari Pekatan Karoten Minyak Sawit Merah Selama Penyimpanan. Konversi, 3(1), 37–45.
- Tan, C. H., Lee, C. J., Tan, S. N., Tik, D., Poon, S., Yi, C., Chong, E., & Pui, L. P. (2022). Red Palm Oil : A Review on Processing , Health Benefits and Its Application in Red Palm Oil : A Review on Processing , Health Benefits and Its Application in Food. August 2021. https://doi.org/10.5650/jos.ess21108
- Widarta, I. W. R., Andarwulan, N., & Haryati, T. (2012). Optimasi Proses Deasidifikasi Dalam Pemurnian Minyak Sawit Merah Skala Pilot Plant. Jurnal Teknologi Dan Industri Pangan, 23(1), 41–46.
- Yupita, M., Budiyanto, B., & Koto, H. (2022). Substitution of Red Palm Oil Olein ( RPOO ) as a Source of Provitamin E in Grilled Meatball Sauce. AGRITROPICA : Journal of Agricultural Sciences, 13–21. https://ejournal.unib.ac.id/index.php/jagritropica/index
Referensi
Arita, S., Anindya, S. A., & Hiranda, W. (2009). Effect of Addition of Acid on the Process of Refining Coarse Castor Oil. Jurnal Teknik Kimia, 16(2), 58–65.
Asyti, F., Oktariani, dan P. M. A. (2020). Kualitas Blend Kelapa Kopra dan Minyak Kelapa Sawit Ditinjau Dari Kadar Air, Kadar Asam Lemak Bebas dan Bilangan Peroksida. Jurnal Riset Kimia, 11(1), 8275–8279.
Bohari, B., Muhadir, M., & Rahmadi, A. (2018). Vacuum evaporation and nitrogen-assisted deodorization affects the antioxidant capacity in the olein fraction of red palm oil and its emulsion products [version 1; peer review: 1 approved with reservations]. F1000Research, 7. https://doi.org/10.12688/F1000RESEARCH.16545.1
Budiyanto, B., Silsia, D., & Napitupulu, A. (2019). Alternatif Fortification Vitamin A for Lactating Mother Using Siomay Sauce Enriched with Red Palm Oil. AGRITROPICA : Journal of Agricultural Sciences, 2(1), 13–25. https://doi.org/10.31186/j.agritropica.2.1.13-25
Budiyanto, Silsia, D., & Fahmi. (2012). Kajian Pembuatan Red Palm Olein(RPOO) Dengan Bahan Baku Minyak Kasar Yang Diambil Dari Beberapa Stasiun Pengolahan Crude Palm Oil. Seminar Nasional Menuju Pertanian Yang Berdaulat, Fakultas Pertanian Universitas Bengkulu, 539–551.
Burri, B. J. (2012). Evaluating Global Barriers to the Use of Red Palm Oil as an Intervention Food to Prevent Vitamin A Deficiency. Comprehensive Reviews in Food Science and Food Safety, 11(2), 221–232. https://doi.org/10.111/j.15414337.2011.00181.x
Chompoo, M, D. Nanthina, and P. R. (2019). Effect Of Chemical Process on Physicochemical Properties of Red Palm Oil. Journal Science Technology, 41(3), 513–521.
Chompoo, M., Damrongwattanakool, N., & Raviyan, P. (2019). Effect of chemical degumming process on physicochemical properties of red palm oil. Songklanakarin J. Sci. Technol., 41(3), 513–521.
Dijkstra, A. J. (2020). About water degumming and the hydration of non-hydratable phosphatides Hypothesis Paper About water degumming and the hydration of non-hydratable phosphatides. October. https://doi.org/10.1002/ejlt.201600496
Kurniati, Y., & Susanto, W. H. (2015). Pengaruh basa NaOH dan kandungan ALB CPO terhadap kualitas minyak kelapa sawit pasca netralisasi t of NaOH and Content of Free Fatty Acid ( FFA ) on. Jurnal Pangan Dan Agroindustri., 3(1), 193–202.
Martianto, D., Andarwulan, N., & Putranda, Y. (2018). Retensi Fortifikan Vitamin A Dan Β-Karoten Dalam Minyak Goreng Sawit Selama Pemasakan. Jurnal Teknologi Dan Industri Pangan, 29(2), 127–136. https://doi.org/10.6066/jtip.2018.29.2.127
Maryuningsih, R. D., & Nurtama, B. (2021). Pemanfaatan Karotenoid Minyak Sawit Merah untuk Mendukung Penanggulangan Masalah Kekurangan Vitamin A di Indonesia.
Musyaroh, M., & Hidayat, N. (2018). The Effect of Stirring Length Time and NaOH Concentration on the Neutralization Process of Superworm Cooking Oil Purification. Industria: Jurnal Teknologi Dan Manajemen Agroindustri, 7(2), 81–88. https://doi.org/10.21776/ub.industria.2018.007.02.2
Ping, B. T. Y., Idris, C. A. C., & Maurad, Z. A. (2020). Oxidative stability of refined red palm olein under two Malaysian storage conditions. Journal of Oleo Science, 69(10), 1209–1218. https://doi.org/10.5650 /jos.ess20045
Riyadi, A., Muchtadi, T. R., Andarwulan, N., & Haryati, T. (2016). Pilot Plant Study of Red Palm Oil Deodorization Using Moderate Temperature. Agriculture and Agricultural Science Procedia, 9, 209–216. https://doi.org/10.1016/j.aaspro.2016.02.129
Robiyansyah, Zuidar, A. S., & Hidayati, S. (2017). Diterima : 27 Januari 2017 Disetujui : 1 Maret 2017. Jurnal Teknologi & Industri Hasil Pertanian, 22(1), 11–20.
Rohmah, M., Rahmadi, A., Yanti, I., Jannah, S. M., Bohari, & Supratman, U. (2021). Quantitation and optimization of β-carotene and α-tocopherol in emulsion prototype with reversed-phase chromatography. Food Research, 5(2), 290–297. https://doi.org/10.26656/fr.2017.5(2).518
Sumarna, D., Sumarlan, S. H., Wijaya, S., & Hidayat, N. (2022). Processing of Olein Fraction Red Palm Oil with Minimal Refining Method and Optimization of Deodorization Process. Proceedings of the International Conference on Tropical Agrifood, Feed and Fuel (ICTAFF 2021), 17(Ictaff 2021), 167–175. https://doi.org/10.2991/absr.k.220102.026
Sumarna, D., Wake, L. S., Suprapto, H., Karakteristik, S., Sawit, M., Karakteristik, S., Sawit, M., Dari, M., Cpo, K., & Palm, C. (2019). Studi Karakteristik Minyak Sawit Merah dari Pengolahan Konvensional CPO (Crude Palm Oil). Jurnal Teknologi Pertanian Universitas Mulawarman, 12(2), 35–38.
Surhaini, S. M., & Yulia, A. (2014). Stabilitas Termal Minuman Emulsi Dari Pekatan Karoten Minyak Sawit Merah Selama Penyimpanan. Konversi, 3(1), 37–45.
Tan, C. H., Lee, C. J., Tan, S. N., Tik, D., Poon, S., Yi, C., Chong, E., & Pui, L. P. (2022). Red Palm Oil : A Review on Processing , Health Benefits and Its Application in Red Palm Oil : A Review on Processing , Health Benefits and Its Application in Food. August 2021. https://doi.org/10.5650/jos.ess21108
Widarta, I. W. R., Andarwulan, N., & Haryati, T. (2012). Optimasi Proses Deasidifikasi Dalam Pemurnian Minyak Sawit Merah Skala Pilot Plant. Jurnal Teknologi Dan Industri Pangan, 23(1), 41–46.
Yupita, M., Budiyanto, B., & Koto, H. (2022). Substitution of Red Palm Oil Olein ( RPOO ) as a Source of Provitamin E in Grilled Meatball Sauce. AGRITROPICA : Journal of Agricultural Sciences, 13–21. https://ejournal.unib.ac.id/index.php/jagritropica/index